API-571 Exam Dumps - API ICP Programs Questions and Answers

API RP 571 describes under Caustic Corrosion:

“One of the significant contributing factors is caustic accumulation in low-flow or stagnant areas, especially in heat-traced lines or around steam injection points.”

“Localized heating can concentrate caustic solutions, promoting corrosion even in carbon or stainless steels.”

Thus, option C (heat-traced equipment) is the correct and technically accurate choice.

API RP 751, which governs HF alkylation units, specifies:

“The total residuals of chromium, nickel, and copper in carbon steel used in HF service should be less than 0.15 wt.% to minimize corrosion risk.”

“Higher residuals increase the reactivity and corrosion rate of carbon steel in the presence of HF acid.”

(Reference: API RP 751, Section 5.3 – Materials Specification for HF Units)

Therefore, option A is the correct choice.

API RP 571, under Chloride Stress Corrosion Cracking, notes:

“Cracking often appears as highly branched or ‘crazed’ networks on the surface, especially in austenitic stainless steels exposed to chlorides under tensile stress.”

“These cracks often initiate in the heat-affected zones or cold-worked areas and are intergranular in nature.”

This signature ‘crazed’ appearance with branching is diagnostic of Cl-SCC, making option C the correct and most descriptive answer.

Comprehensive and Detailed Explanation From Exact Extract:

Hydrochloric acid (HCl) corrosion in atmospheric crude units is primarily associated with the overhead system, where chloride salts hydrolyze to form HCl in the presence of condensed water. This damage mechanism is well documented in API RP 571 under “Chloride Stress Corrosion Cracking and Hydrochloric Acid Corrosion”.

The primary indicator of HCl corrosion risk is the acidity of the condensed water in the overhead system. The overhead accumulator boot water collects condensed water where dissolved HCl will be present. Monitoring the pH of this water provides a direct, real-time indication of acid formation and corrosion severity.

Low pH values (typically below 5.5) indicate active HCl corrosion conditions.

API RP 571 states that pH monitoring is a key operational control and surveillance tool for managing overhead corrosion.

Why the other options are incorrect:

Option A (UT at water injection points) does not address overhead acid formation and is not a susceptibility monitoring method.

Option C (Corrosion probes or coupons) provide general corrosion rate data, but they do not directly measure HCl formation or acid severity and often respond too slowly for operational control.

Option D (UT scanning or radiography) is a damage detection method, not a susceptibility or early-warning monitoring technique.

API RP 571 emphasizes that effective monitoring of HCl corrosion requires controlling and monitoring water chemistry, especially pH in the overhead accumulator boot, to prevent severe localized corrosion and ammonium chloride salt deposition.

Referenced Documents (Study Basis):

API RP 571 – Section on Hydrochloric Acid Corrosion in Crude Unit Overhead Systems

API Corrosion and Materials Study Guides – Atmospheric Crude Unit Overhead Corrosion

According to API RP 571, under the section "Corrosion in Aqueous Environments – Cooling Water Corrosion", one of the key contributors to corrosion in carbon steel and other materials used in heat exchangers is the presence of dissolved oxygen. API RP 571 states:

"Oxygen is a primary contributor to corrosion in cooling water systems. Systems open to the atmosphere are typically more corrosive than closed systems due to the continual replenishment of oxygen."

"Corrosion rates are highest where oxygen concentration is the greatest, especially in systems using untreated or poorly treated water."

"Carbon steel corrodes in the presence of oxygen and water, forming corrosion products that may or may not adhere to the surface."

(Reference: API RP 571, Section 4.3.1.1 – Cooling Water Corrosion)

Therefore, increasing oxygen content directly increases corrosion activity in exchanger tubes, making option C the correct and documented answer.

API RP 571 discusses this under Wet H₂S Damage – Hydrogen Blistering, HIC, SOHIC:

“Hydrogen generation is reduced as pH increases. At pH 9 and above, the corrosion potential is less favorable for hydrogen charging and thus permeation into the steel is minimal.”

“Most wet H₂S cracking damage mechanisms are accelerated under acidic conditions (pH < 7).”

Hence, high pH (around 9) environments offer the most protection against hydrogen damage, making option D the correct choice.

According to API RP 571, high-cycle fatigue (HCF) is characterized by very tight, narrow cracks that can escape detection using typical NDE methods due to their minimal opening displacement and fine geometry.

From API RP 571 Section 5.2.1 (Fatigue - High Cycle):

"The cracks are usually tight and may be difficult to detect using conventional NDE techniques such as PT or MT. UT and RT may also have difficulty identifying these small, tight flaws, especially in early stages of propagation."

The primary issue in NDE is not the geometry (such as 90° corners) or ID location, but rather the tightness and early-stage subtlety of the cracks which results in reduced detectability. Therefore, option B is correct as it aligns most accurately with API RP 571's detailed characterization of HCF detection challenges.

API RP 571 discusses Hydrogen-Induced Cracking (HIC) and Blistering under the section:

“HIC and blistering are most strongly influenced by non-metallic inclusions, particularly elongated manganese sulfide (MnS) inclusions, which serve as trap sites for hydrogen atoms.”

“These inclusions create local planes of weakness where atomic hydrogen recombines into molecular hydrogen (H₂), causing high pressure and cracking.”

(Reference: API RP 571, Section 4.2.2.7 – Hydrogen Blistering and HIC)

Thus, inclusions are the critical material factor, making option A correct.

API RP 571 on Brittle Fracture notes:

“The primary factor influencing brittle fracture is material toughness, especially at low temperatures.”

“Materials with low fracture toughness are susceptible to catastrophic failure when stressed below their ductile-to-brittle transition temperature.”

Hence, option A is correct.

According to API RP 571, Section 4.2.1.1 – Sulfidation, and also echoed in API RP 939-C, the presence of certain compounds significantly increases sulfidic corrosion:

“Chlorides are known to accelerate sulfidation and other high-temperature corrosion mechanisms by forming low-melting eutectics and breaking down protective scales on alloy surfaces.”

“Chlorine-containing species also interfere with the formation of stable sulfide or oxide scales, leading to more aggressive metal loss.”

Therefore, chlorides are the most critical accelerant among the listed substances in high-temperature sulfur compound environments, making option C correct.